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Synthetic diamond

Synthetic diamond is diamond produced in a technological process, as opposed to natural diamond which is created in geological processes. Synthetic diamond is also widely known as HPHT diamond or CVD diamond where HPHT and CVD refer to the production method, namely high-pressure high-temperature synthesis and chemical vapor deposition, respectively.

Numerous claims of diamond synthesis were documented between 1879 and 1928; every attempt has been carefully analyzed and none has been confirmed. In the 1940s, systematic research began in the United States, Sweden and the Soviet Union to grow diamond using CVD and HPHT processes. The first reproducible synthesis was reported around 1953. Those two processes still dominate the production of synthetic diamond. A third method, known as detonation synthesis, has entered the diamond market in the late 1990s. In this process, nanometer-sized diamond grains are created in a detonation of carbon-containing explosives. A fourth method, treating graphite with high-power ultrasonic radiation, has been demonstrated in the laboratory, but as yet there is no commercial application.

The properties of synthetic diamond depend on the details of the manufacturing processes, and can be inferior or superior to those of natural diamond; the hardness, thermal conductivity and electron mobility are superior in some synthetic diamonds (either HPHT or CVD). Consequently, synthetic diamond is widely used in abrasives, cutting and polishing tools and in heat sinks. Electronic applications of synthetic diamond are being developed, including high-power switches at power stations, high-frequency field-effect transistors and light-emitting diodes. Synthetic diamond detectors of ultraviolet (UV) light or high-energy particles are used at high-energy research facilities and are available commercially. Because of its unique combination of thermal and chemical stability, low thermal expansion and high optical transparency in a wide spectral range, synthetic diamond is becoming the most popular material for optical windows in high-power CO2 lasers and gyrotrons.

Both CVD and HPHT diamonds can be cut into gems and various colors can be produced: clear white, yellow, brown, blue, green and orange. The appearance of synthetic gems on the market created major concerns in the diamond trading business, as a result of which special spectroscopic devices and techniques have been developed to distinguish synthetic and natural diamonds.

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